MSDS Identification:

• Key:  08167
• Name:   Antimony Trifluoride, 98%

Catalog Numbers:  
AC191240000, AC191240050, AC191241000, AC191245000
Synonyms:  

• Antimonous Trifluoride; Trifluoroantimony.

SUPPLIER: ZHANGJIANG DONGYAN GALT FINE CHEMCAL CO., LTD.
BUSINESS TEL: ++86-579-6530757
FACSIMILE: ++86-579-6530756

Hazard Symbols:   T N

Risk Phrases:   23/24/25 51/53

EMERGENCY OVERVIEW

Appearance:   white solid. Danger! Corrosive. Water-Reactive. May cause severe respiratory tract irritation with possible burns. May cause severe digestive tract irritation with possible burns. May cause skeletal abnormalities. Reacts with water to produce toxic and corrosive hydrogen fluoride.

Target Organs:   Blood, liver, skeletal structures, nerves.
POTENTIAL HEALTH EFFECTS

Eye:   When substance becomes wet or comes in contact with moisture of the mucous membranes, it will cause irritation. May cause chemical conjunctivitis and corneal damage.

Skin:   Contact with skin causes irritation and possible burns, especially if the skin is wet or moist. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.

Ingestion:   May cause severe and permanent damage to the digestive tract. May cause liver damage. May cause perforation of the digestive tract. Inorganic fluorides can be harmful. Acute exposure to fluorine compounds can lead to digestive tract burns, and abdominal pain. Contains fluoride. Fluoride can reduce calcium levels leading to fatal hypocalcemia. May cause systemic effects.

Inhalation:   Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Aspiration may lead to pulmonary edema. May cause systemic effects.

Chronic:   Chronic inhalation and ingestion may cause chronic fluoride poisoning (fluorosis) characterized by weight loss, weakness, anemia, brittle bones, and stiff joints. Chronic inhalation may cause nasal septum ulceration and perforation. Effects may be delayed. Chronic exposure to fluoride compounds may cause systemic toxicity.

Eyes:   Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).

Skin:   Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. If water-reactive products are embedded in the skin, no water should be applied. The embedded products should be covered with a light oil.

Ingestion:   Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation:   Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.

Notes to Physician:   Treat symptomatically and

General Information:   As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Not flammable, but reacts with most metals to form flammable hydrogen gas. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Use water spray to keep fire-exposed containers cool. Containers may explode when heated or if contaminated with water. When heated to decomposition, Antimony Trifluoride emits very toxic fumes of Hydrogen Fluoride and antimony.

Extinguishing Media:   If water is the only media available, use in flooding amounts. Do NOT get water inside containers. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Most foams will react with the material and release corrosive/toxic gases. Contact professional fire-fighters immediately. Cool containers with flooding quantities of water until well after fire is out. For small fires, use carbon dioxide (except for cyanides), dry chemical, dry sand, and alcohol-resistant foam.

Autoignition Temperature:   Not applicable.

Flash Point:   Not applicable.

Explosion Limits, lower:   Not available.

Explosion Limits, upper:   Not available.

NFPA Rating:   (estimated) Health: 3; Flammability: 0; Instability: 1; Specia

General Information:   Use proper personal protective equipment as indicated in Section 8.

Spills/Leaks:   Vacuum or sweep up material and place into a suitable disposal container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Do not expose spill to water.

Handling:   Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Do not allow water to get into the container because of violent reaction. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not allow contact with water. Use only in a chemical fume hood. Discard contaminated shoes. Keep from contact with moist air and steam.

Storage:   Store in a cool, dry place. Keep container closed when not in use. Store in a tightly closed container. Keep away from water. Corrosives area.

Engineering Controls:   Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
EXPOSURE LIMITS

OSHA Vacated PELs:  

Antimony Trifluoride:   0.5 mg/m3 TWA (listed under ** no name **)2.5 mg/m3 TWA (listed under ** no name **)0.5 mg/m3 TWA (as Sb) (listed under ** no name **)
PERSONAL PROTECTIVE EQUIPMENT

Eyes:   Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Skin:   Wear appropriate protective gloves to prevent skin exposure.

Clothing:   Wear appropriate protective clothing to prevent skin exposure.

Respirators:   A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Physical State:   Solid

Color:   white

Odor:   Odorless.

pH:   Not available.

Vapor Pressure:   26kpa @ .26atm

Vapor Density:   Not available.

Evaporation Rate:   Not available.

Viscosity:   Not available.

Boiling Point:   376 deg C

Freezing/Melting Point:   292 deg C

Decomposition Temperature:   Not available.

Solubility in water:   Soluble in water.

Specific Gravity/Density:   4.38

Molecular Formula:   F3Sb

Molecular Weight:   178.7052

Chemical Stability:   Stable under normal temperatures and pressures. Combines vigorously or explosively with water. Reaction with water generates much heat, which will increase the concentration of fumes, hydrogen fluoride and antimony, in the air.

Conditions to Avoid:   Incompatible materials, dust generation, exposure to moist air or water.

Incompatibilities with Other Materials:   Strong oxidizing agents, perchloric acid, water.

Hazardous Decomposition Products:   Irritating and toxic fumes and gases, hydrogen fluoride, antimony/antimony oxides.

Hazardous Polymerization:   Has not been reported

RTECS#:

• CAS# 7783-56-4: CC5150000

LD50/LC50:

• CAS# 7783-56-4: Oral, mouse: LD50 = 804 mg/kg.

Carcinogenicity:
Antimony Trifluoride -

• ACGIH: A4 - Not Classifiable as a Human Carcinogen (as F) (listed IARC: Group 3 carcinogen (listed as ** undefined **).

Epidemiology:
No information found.
Teratogenicity:
No information found.
Reproductive Effects:
No information found.
Neurotoxicity:
No information found.
Mutagenicity:
No information found.
Other Studies:
See actual entry in RTECS for complete information.

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.

RCRA P-Series:   None listed.

RCRA U-Series:   None listed.

US DOT

• Shipping Name: Not regulated.
• Hazard Class:
• UN Number:
• Packing Group:

Canadian TDG

• No information available.

TSCA

• CAS# 7783-56-4 is listed on the TSCA inventory.

Health & Safety Reporting List

• None of the chemicals are on the Health & Safety Reporting List.

Chemical Test Rules

• None of the chemicals in this product are under a Chemical Test Rule.

Section 12b

• None of the chemicals are listed under TSCA Section 12b.

TSCA Significant New Use Rule

• None of the chemicals in this material have a SNUR under TSCA.

SARA
CERCLA Hazardous Substances and corresponding RQs

• CAS# 7783-56-4: 1000 lb final RQ; 454 kg final RQ

SARA Section 302 Extremely Hazardous Substances

• None of the chemicals in this product have a TPQ.

Section 313

• This material contains Antimony Trifluoride (listed as ** undefined **), 98%, (CAS# 7783-56-4) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 372.

Clean Air Act:

• CAS# 7783-56-4 listed as ** no name ** is listed as a hazardous air pollutant (HAP).
• This material does not contain any Class 1 Ozone depletors.
• This material does not contain any Class 2 Ozone depletors.

Clean Water Act:

• CAS# 7783-56-4 is listed as a Hazardous Substance under the CWA.
• CAS# 7783-56-4 is listed as a Priority Pollutant under the Clean Water Act.
• CAS# 7783-56-4 is listed as a Toxic Pollutant under the Clean Water Act.

OSHA:

• None of the chemicals in this product are considered highly hazardous by OSHA.

Antimony Trifluoride can be found on the following state right to know lists: California, New Jersey, Florida, (listed as ** no name **), Pennsylvania, Minnesota, (listed as ** no name **), Minnesota, (listed as ** no name **), Minnesota, (listed as ** no name **), Minnesota, (listed as ** no name **), Massachusetts.

California No Significant Risk Level: None of the chemicals in this product are listed.

European Labeling in Accordance with EC Directives

• Hazard Symbols: T N
• Risk Phrases:

• R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
• R 51/53 Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment.

• Safety Phrases:

• S 7 Keep container tightly closed.
• S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
• S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
• S 61 Avoid release to the environment. Refer to special instructions/Safety data sheets.

WGK (Water Danger/Protection)

• CAS# 7783-56-4: No information available.

United Kingdom Occupational Exposure Limits

• CAS# 7783-56-4: OES-United Kingdom, TWA (listed as ** undefined **): 2.5 mg/m3 TWA (inorganic, as F)

United Kingdom Maximum Exposure Limits

• CAS# 7783-56-4: MEL-United Kingdom, TWA (listed as ** undefined **): 0.5 mg/m3 TWA (as Sb, except stibine)

Canada

• CAS# 7783-56-4 is listed on Canada's DSL List.
• This product has a WHMIS classification of E, B6.
• CAS# 7783-56-4 is not listed on Canada's Ingredient Disclosure List.

Exposure Limits

• CAS# 7783-56-4: OEL-ARAB Republic of Egypt:TWA 0.5 mg(Sb)/m3
• OEL-AUSTRALIA:TWA 0.5 mg(Sb)/m3
• OEL-AUSTRALIA:TWA 2.5 mg(F)/m3
• OEL-AUSTRIA:TWA 0.5 mg(Sb)/m3
• OEL-BELGIUM:TWA 0.5 mg(Sb)/m3
• OEL-BELGIUM:TWA 2.5 mg(F)/m3
• OEL-CZECHOSLOVAKIA:TWA 0.5 mg(Sb)/m3;STEL 2.5 mg(Sb)/m3
• OEL-CZECHOSLOVAKIA:TWA 1 mg(F)/m3;STEL 5 mg(F)/m3
• OEL-DENMARK:TWA 0.5 mg(Sb)/m3
• OEL-DENMARK:TWA 2.5 mg(F)/m3
• OEL-FINLAND:.TWA (0.5 mg(Sb)/m3)
• OEL-FINLAND:TWA 2.5 mg(F)/m3
• OEL-FRANCE:TWA 0.5 mg(Sb)/m3
• OEL-FRANCE:TWA 2.5 mg(F)/m3
• OEL-GERMANY:TWA 0.5 mg(Sb)/m3 (total dust)
• OEL-GERMANY:TWA 2.5 mg(F)/m3
• OEL-HUNGARY:STEL 0.5 mg(Sb)/m3
• OEL-HUNGARY:TWA 1 mg(F)/m3;STEL 2 mg(F)/m3
• OEL-THE NETHERLANDS:TWA 0.5 mg(Sb)/m3
• OEL-THE NETHERLANDS:TWA 2.5 mg(F)/m3
• OEL-THE PHILIPPINES:TWA 0.5 mg(Sb)/m3
• OEL-THE PHILIPPINES:TWA 2.5 mg(F)/m3
• OEL-POLAND:TWA 0.5 mg(Sb)/m3
• OEL-POLAND:TWA 1 mg(F)/m3
• OEL-RUSSIA:STEL 0.3 mg/m3
• OEL-RUSSIA:TWA 0.2 mg(Sb)/m3;STEL 0.5 mg(Sb)/m3
• OEL-SWEDEN:TWA 0.5 mg(Sb)/m3
• OEL-SWEDEN:TWA 2 mg(F)/m3
• OEL-SWITZERLAND:TWA 0.5 mg(Sb)/m3
• OEL-SWITZERLAND:TWA 1.8 ppm (1.5 mg(F)/m3);STEL 9.0 ppm

MSDS Creation Date:   2/11/1999,   Revision #5 Date:  6/13/2002
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages